The star-packed lineup for “The 45th Annual CMA Awards” grows with today’s announcement that co-hosts Brad Paisley and Carrie Underwood will perform their   duet “Remind Me” on “Country Music’s Biggest Night(tm).” This will be their first live performance of the No. 1 hit song on national television.

“The 45th Annual CMA Awards,” hosted by Paisley and Underwood, airs live from the Bridgestone Arena in Nashville, Wednesday, Nov. 9 (8:00-11:00 PM/ET) on the ABC Television Network. Previously announced performers include Jason Aldean, Blake Shelton, Taylor Swift, and Keith Urban